Unsaturated polyester compounds, resins curable with actinic energy ray, processes for the production thereof, and curable compositions

   
   

An unsaturated polyester compound having an ethylenically unsatureated group in its terminal and hydroxymethyl group in its side chain is obtained by the reaction of (a) a compound containing at least two oxetane rings in its molecule with (b) a compound containing at least two carboxyl groups in its molecule and (c) an unsaturated monocarboxylic acid in the presence of a reaction promotor in such a proportion that the ratio of said compound (b) to said compound (a) falls in the range of 0.1(b)/(a)1. BY further reacting (d) a polybasic acid anhydride with the resultant unsaturated polyester compound (A), there is obtained an actinic energy ray-curable resin which is soluble in an aqueous alkaline solution. A photocurable and/or thermosetting composition is obtained by mixing the unsaturated polyester compound (A) and/or the actinic energy ray-curable resin with a polymerization initiator (B).

 
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