The present invention relates to a process for the reductive dehalogenation of halogenated hydrocarbons. It comprises reacting halogenated hydrocarbons with a reducing metal and a hydrogen donating compound in the presence of an amine. Preferably, the halogenated hydrocarbons are reacted with lithium, potassium, calcium, sodium, magnesium, aluminum, zinc or iron. Depending on the metal, the complete reductive dehalogenation takes place at temperatures ranging from room temperature to 400.degree. C.