An improved catalytic composition for oligomerization, in particular dimerization, of monoolefins comprises the product resulting from bringing the following three constituents into contact in any order: a) at least one divalent nickel compound; b) at least one hydrocarbylaluminium dihalide, optionally enriched with an aluminum trihalide; and c) at least one organic Bronsted acid;the catalytic composition being pre-conditioned in a solvent before using it for oligomerization.

 
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