A data/information storage and retrieval medium comprises: (a) a substrate having a layer stack thereon, the layer stack including an outer surface and comprising at least one magnetic or magneto-optical ("MO") recording layer; and (b) a thin film or layer of a lubricant on the outer surface of the layer stack and comprised of a derivatized perfluoropolyether-based material including at least one generally linear perfluoropolyether chain and at least one phosphite antioxidant/stabilizer moiety attached to at least one end of at least one the chain.