An ion adsorption electrode having large electrical capacity and ion adsorption capacity, an electosorption purification device having the same, and a method of manufacturing the ion adsorption electrode, the ion adsorption electrode including active carbon, a binder and an ion exchange resin. The electosorption purification device includes: an anode adsorbing and desorbing anions among inorganic ions in water; a cathode, facing the anode, adsorbing and desorbing cations among inorganic ions in water; and a direct current supply respectively applying voltages to the anode and cathode, where the anode and cathode may include the active carbon, binder and ion exchange resin. The method of manufacturing the ion adsorption electrode includes: preparing a mixture by mixing active carbon powder, a binder and an ion exchange resin with each other; and forming the mixture in a predetermined thickness by pressing the mixture.