The present invention relates, generally, to the art of impregnating metal complexes into anion exchange materials to provide improved anion exchange materials with a metal inside the materials such that the modified materials effectively and efficiently remove or recover various metals, including metal containing complexes, compounds, and contaminants, such as arsenic, from, for example, process solutions, effluents and aqueous solutions. Uses for the improved anion exchange materials are also described as are methods of making modified anion exchange materials, and methods of removing and recovering at least one metal or contaminant from a source.