Paint systems, in accordance with exemplary embodiments, of the present invention include a foundation base component and a top coat component. The foundation base component is tinted to match the top coat component to provide both the desired amount of hiding of colors or markings on the substrate to which the paint system is applied, and to enhance the brightness and hue of the color of the paint system. Furthermore, in another innovative aspect of the present invention, the foundation base component comprises at least one low molecular weight polymer that undergoes self-crosslinking at ambient conditions during and after paint drying. The low molecular weight polymer penetrates various substrates, including chalky surfaces, to provide improved adhesion. Moreover, because the low molecular weight polymer is self-crosslinking at ambient conditions, the polymer enhances the performance of dried paints, including improving mechanical strength, tannin block properties, and weatherability.