Provided is a real-time business process triggering system (RBPTS) using a Radio Frequency Identification (RFID) and a method thereof. The RBPTS is to provides interface to a corporation information system by generating an RFID event proper to a specific domain by giving the RFID data a business meaning to apply the RFID data to a predetermined rule before transmitting the RFID data to the corporation information system, provide a rule modeling function to flexibly managing changes in application field and environment, and provide an RFID related-action related to rule performance, and a method thereof. The RBPTS includes: an RFID middleware adapter for receiving RFID data from an RFID middleware/RFID reader and generating RFID events Extensible Markup Language (XML) document; an event manager for receiving the RFID events XML document from the RFID middleware adapter and generating an event query for inference; a rule manager for generating a result set by performing rule inference on the event query through an inference engine and generating an action list; Web Service arbitrator for communicating through Web Service using an external application and a Simple Object Access Protocol (SOAP); an action manager for performing real-time action by calling the Web Service through the Web Service arbitrator based on the action list; and an event repository for storing and managing registered all RFID event information, rule and action. The RBPTS is applied to maritime freight transportation.