Additives for paper making are disclosed herein. Specifically, the
additives are wax-free alternatives to conventional coatings, including
ASA, AKD and optionally an acrylic containing composition. Other
additives may be included in the coating, such as cationic particles or
compositions. The coatings may be used at a variety of points during the
paper making process, including on the calender stack and in the wet end.