An environmental protection paper material structure for food containers and its manufacturing method include a paper layer roll printed and coated with a first crosslinker coating in compliance with the laws and regulations of an adhesive for food packaging on both surfaces by a roll printing method, and a biodegradable material layer coated on the surface of the two first crosslinker coatings by a film coating method, and a second crosslinker coating and an anti-adhesive coating roll-printed and coated on upper and lower external layers. The anti-adhesive coating at the external layer effectively prevents the biodegradable material layer from being in a direct contact with the moisture in the air or becoming sticky due to a temperature rise before the environmental paper material is cut into different shapes of paper containers or rolled or stacked for storage, and the paper material can be used directly for hot pressing and shaping.