The present invention provides a pyrolysis system and method thereof which are capable of converting an entire rubber tire into several energy resources in an environmentally-friendly manner. The system includes a tire transporting unit, a waste to energy conversion unit, and a energy collection unit. The waste to energy conversion unit includes a conversion housing having a reaction chamber for receiving the rubber tire for pyrolysis processing to decompose the rubber tire into fuel oil, methane gas and carbon black, while metal wire from the rubber tire are resided for recycling use.