A method of automatically determining a measure of atmospheric aerosol optical properties using a multi- or hyper-spectral, multi-pixel image. A plurality of spectrally-diverse pixels are resolved from the image. A statistical spectral deviation of the spectrally-diverse pixels is determined, and then corrected for non-aerosol transmittance losses. One or more wavelength-dependent aerosol optical depths are derived from the statistical spectral deviation. Wavelength-dependent gaseous optical depths can be derived from the statistical spectral deviation.