Metal nanoparticle thermoset and carbon compositions from mixtures of metallocene-aromatic-acetylene compounds

   
   

The present invention provides for a composition comprising:

    • a composition formed by heating to a temperature of from about 300 C. and above a mixture of:
    • an organometallic composition and an aromatic-acetylene containing compound; and
    • wherein said organometallic composition comprises the formula: ##STR1##
    •  wherein A is selected from the group consisting of H, ##STR2##

      and ##STR3##

    • wherein M is a metal;
    • wherein Rx and Ry are independently selected from the group consisting of an aromatic, a substituted aromatic group and combinations thereof;
    • wherein m, s and z are 0;
    • wherein m and s are independently determined in each repeating unit;
    • wherein said aromatic-acetylene containing composition is 1,2,4,5-tetrakis(phenylethynyl)benzene, 1,2,4-tris(phenylethynyl)benzene or 1,3,5-tris(phenylethynyl)benzene; and
    • wherein said organometallic composition and said aromatic-acetylene composition are molar mix proportions of between 1 and 99 of said organometallic composition and between 99 and 1 of said aromatic-acetylene composition.
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