Catalytic partial oxidation using staged oxygen addition

   
   

A multistage catalytic partial oxidation (CPO) process for oxidizing a hydrocarbon feedstream comprising C.sub.1 -C.sub.4 hydrocarbons, with an oxygen-containing feedstream to produce a product comprising CO and H.sub.2, also known as synthesis gas or syngas. The process employs a CPO catalyst, and controlled process features, including: (A) the total oxygen requirement for the process is introduced incrementally, in more than one reaction stage, using an oxygen-containing feedstream at more than one feed point in the process, each stage including a catalyst; (B) the oxygen-containing feedstream, hydrocarbon feedstream and, in reaction stages after the first of said multiple stages, the intermediate product produced in the prior stage, are mixed for a period of time, after they are brought into contact with one another, of less than about 1 millisecond to form a substantially uniform mixture, wherein the mixture is then contacted with the catalyst; (C) the oxygen-containing feedstream and the hydrocarbon feedstream are preheated prior to entry into the first stage, to a temperature of from about 450.degree. C. to less than about 1,000.degree. C.; and (D) the mixture temperature of the product in each stage following the first stage is from greater than about 600.degree. C. to less than about 1,000.degree. C. Preferably, the process comprises less than or equal to about five stages, the first stage preheat temperature recited in step (C) is greater than about 550.degree. C. and the mixture temperature of the product in each stage following the first stage is at least 700.degree. C.

 
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