A silica-based optical fiber includes a core and a cladding that is formed on an outer circumference of the core. The core includes three or more layers including a layer doped with at least one of germanium and fluorine, and a concentration of the germanium or the fluorine in each of the layers is controlled in such a manner that a Brillouin gain spectral peak is spread into a plurality of peaks on a Brillouin gain spectrum. With this scheme, an optical fiber is provided, which has stable characteristics in the longitudinal direction, and which has a high SBS threshold so that generation of the SBS can be effectively suppressed.