Embodiments in accordance with the present invention provide for forming
essentially pure diastereomers of 5/6-substituted norbornene-type
monomers. Further, embodiments in accordance with the present invention
encompass polymerizing such diastereomers to form addition or ROMP
polymers where a desired exo-/endo-ratio of the diastereomers is provided
to the polymerization, such ratio designed to provide a desired ratio of
endo-/exo-structured repeating units for a resulting polymer to have
desired physical or chemical properties.