A PWM controller compensates a maximum output power of a power converter, and includes a PWM unit and a compensation circuit. The PWM unit generates a PWM signal for controlling a power switch to switch a power transformer, which has a primary winding connected to the power switch and is supplied with an input voltage of the power converter. A pulse width of the PWM signal is correlated to an amplitude of the input voltage. The compensation circuit generates a current boost signal in response to the PWM signal by pushing up a peak value of a current-sense signal generated by a current-sense device in response to a primary-side switching current of the power transformer. A peak value of the current boost signal is adjusted by the pulse width of the PWM signal for compensating a difference of the maximum output power caused by the amplitude of the input voltage.