In various embodiments of the invention, novel compositions having a polynucleotide bound to a substrate via a cleavable linker are provided, and methods of cleaving a polynucleotide from a substrate are provided.

 
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> Method for the preparation of 2-halo-2'-deoxyadenosine compounds from 2'-deoxyguanosine

> Dithiocarbonate containing macromers and polymers derived therefrom
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