Methods and apparatus for distributed temperature sensing (DTS) along a single mode or multimode optical waveguide or fiber include a calibration of initial Brillouin-based DTS measurements using Raman-based DTS measurements to enable accurate subsequent Brillouin-based DTS measurements. Such calibration may occur while the fiber is deployed in the environment in which temperature is to be sensed and thereby corrects influences on Brillouin scattered light from stress or strain along the fiber. Further, calibration may utilize one or more discrete temperature sensors to correct errors in one or both of the Brillouin-based DTS measurements and the Raman-based DTS measurements.