An exhaust system of an internal combustion engine having at least one cylinder comprises a main exhaust passage connected to the cylinder; a main catalytic converter disposed in the main exhaust passage; a bypass exhaust passage that diverges from the main exhaust passage, the bypass exhaust passage having a gas flow resistance larger than that of the main exhaust passage and having a downstream end connected to the main exhaust passage at a position upstream of the main catalytic converter; an auxiliary catalytic converter disposed in the bypass exhaust passage; and a gas flow switching device that is capable of forcing exhaust gas from the cylinder of the engine to flow toward the bypass exhaust passage when assuming a given operation position.