Thermally tunable optical sensors are used in sampling tools for analysis of samples from a wellbore. The thermally tunable optical sensors generate a series passbands of wavelength emissions and detect attenuation in a signal thereof. The attenuation detected is processed and used to determine aspects of the samples. Analysis may be completed remotely (outside of the wellbore), within the wellbore (during drilling or otherwise), or as a part of another process such as fluid management, transport and refinement.