A magnet assembly comprising first and second sets of coils (1, 2) for generating respective magnetic fields, wherein the coils are constructed and arranged such that under working conditions, a first homogeneous region (3) can be generated within the envelope defined by the magnet 10 assembly and a second homogeneous region (4) can be generated outside the envelope, the resultant magnetic field in each region being sufficiently homogeneous to enable a NMR process to be performed on an object in the region.