A radio frequency identification (RFID) system having the capacity to detect various geometric parameters of alignment. The described system is configured for use with dental x-ray, medical imaging and treatment, and customary and digital radiography apparatus, but is not restricted to such apparatus or applications. The system may include a multiplicity of RF transponders, RF tags, and RF readers, wherein each RF tag may include one or more carrier receive/data transmit coils and wherein each RF reader may include one or more carrier transmit/data receive coils, and wherein each coil of an RF tag or RF reader may resonate at one or more, and/or, at the same or differing frequencies. An RF tag located about an x-ray sensitive film or device, and an RF reader located about a dental x-ray machine or apparatus, are configured to be critically aligned, one to the other, rendering repeat imaging unnecessary.