The present invention provides an optical waveguide, which at least includes: a waveguide core having a cavity therein; and a clad which encloses the periphery of the waveguide core and has a smaller refractive index than the waveguide core, wherein the optical waveguide changes a direction of a part or all of propagated light by using a part or all of an interface between the waveguide core and the cavity as a reflecting surface. The present invention further provides a method for manufacturing the optical waveguide, which at least includes: forming a core having a cavity therein on a substrate; applying an uncured clad material to a side surface and an upper portion of the core while maintaining the cavity which allows an atmospheric gas to be present in the cavity; and curing the clad material by heat or light to seal the gas in the cavity.