Production processes and systems are provided that include reacting halogenated compounds, dehalogenating compounds, reacting alcohols, reacting olefins and a saturated compounds, reacting reactants having at least two --CF.sub.3 groups with reactants having cyclic groups. R.sub.F-compositions such as R.sub.F-intermediates, R.sub.F-surfactants, R.sub.Fmonomers, R.sub.F-monomer units, R.sub.F-metal complexes, R.sub.F-phosphate esters, R.sub.F-glycols, R.sub.F-urethanes, and/or R.sub.F-foam stabilizers. The R.sub.F portion can include at least two CF.sub.3 groups, at least three --CF.sub.3 groups, and/or at least two --CF.sub.3 groups and at least two --CH.sub.2-- groups. Detergents, emulsifiers, paints, adhesives, inks, wetting agents, foamers, and defoamers including the R.sub.F-surfactant composition are provided. Acrylics, resins, and polymers are provided that include a R.sub.F-monomer unit. Compositions are provided that include a substrate having a R.sub.F-composition thereover. Aqueous Film Forming Foam ("AFFF") formulations are provided that can include R.sub.Fsurfactants and/or R.sub.F-foam stabilizers are provided.