The bulk synthesis of highly crystalline noncatalytic low melting metals
such as .beta.-gallium oxide tubes, nanowires, and nanopaintbrushes is
accomplished using molten gallium and microwave plasma containing a
mixture of monoatomic oxygen and hydrogen. Gallium oxide nanowires were
20 100 nm thick and tens to hundreds of microns long. Transmission
electron microscopy (TEM) revealed the nanowires to be highly crystalline
and devoid of any structural defects. Results showed that multiple
nucleation and growth of gallium oxide nanostructures can occur directly
out of molten gallium exposed to appropriate composition of hydrogen and
oxygen in the gas phase. These gallium oxide nanostructures are of
particular interest for opto-electronic devices and catalytic
applications.