A method of providing a fire barrier that includes coating an opening in a structure with a composition that includes an elastomer. The composition is substantially free of volatile organic compounds and, when dry, exhibits a tensile strength of from about 300 psi to about 1500 psi, at least about 600% elongation, a modulus of from about 200 psi to about 600 psi, and a tensile toughness of greater than 10 in-lb.