A system of classifying incoming media entering an inkjet printing mechanism identifies transparency media without requiring any special manufacturer markings. The media is first optically scanned using a blue-violet light at an initial intensity to obtain both diffuse and specular reflectance data. If useable, the data is compared with known values to classify the media so an optimum print mode tailored for the particular media is used. The early transparency detection system avoids time-consuming further steps trying to classify the media as photo media, plain paper, and the like, and facilitates fast printing of transparencies, which can be critical in the business environment when making last minute changes for a presentation. A printing mechanism constructed to implement this method is also provided.