Superconducting bismuth-strontium-calcium-copper oxide compositions and process for manufacture

   
   

Compositions having the nominal formula Bi.sub.a Sr.sub.b Ca.sub.c Cu.sub.3 O.sub.x wherein a is from about 1 to 3, b is from about 3/8 to 4, c is from about 3/16 to 2, x=(1.5 a+b+c+y) where y is from about 2 to 5, with the proviso that "b+c" is from about 3/2 to 5, containing a metal oxide phase of the formula Bi.sub.2 Sr.sub.3-z Ca.sub.z Cu.sub.2 O.sub.8+w wherein z is from about 0.1 to 0.9 w is greater than zero but less than 1, are superconducting. Processes for manufacturing such compositions and for using them are disclosed.

Составы имея штатную формулу Bi.sub.a Sr.sub.b Ca.sub.c Cu.sub.3 O.sub.x при котором а от около 1 к 3, б от около 3/8 к 4, ч от около 3/16 к 2, x=(1.5 a+b+c+y) где ы от около 2 к 5, with the proviso that "b+c" от около 3/2 к 5, содержащ участок окиси металла формулы Bi.sub.2 Sr.sub.3-z Ca.sub.z Cu.sub.2 O.sub.8+w при котором з от около от 0.1 до 0.9 ш greater than нул но меньш чем 1, superconducting. Показаны процессы для изготовлять такие составы и для использования их.

 
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