Method for producing alcoxylated carbonyl compounds by an anodic oxidation method using a cathodic coupled reaction for organic synthesis

   
   

A method for producing alcoxylated carbonyl compounds of general formula (I) (compounds I): R.sup.1.sub.a R.sup.2 C(OR.sup.3).sub.b wherein R.sup.1, R.sup.2 represent hydrogen or C.sub.1 -C.sub.6 -alkyl, R.sup.3 independently means C.sub.1 -C.sub.6 -alkyl, a is 0 or 1, b 2 or 3 with the proviso that the sum of a and b is 3, by means of anodic oxidation of germinal dialcoxy compounds of general formula (II) (compounds II) wherein R.sup.4, R.sup.5, R.sup.6, R.sup.7 represent hydrogen or C.sub.1 -C.sub.6 -alkyl, R.sup.5, R.sup.6 represent C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -alcoxy, in the presence of a C.sub.1 -C.sub.6 -alkyl alcohol (compounds III). A usual compound (compound IV) is used as a cathodic depolarizer suitable for electrochemical oxidation. The anodic oxidation and cathodic reduction is carried out in an undivided electrolyte cell in the presence of C.sub.1 -C.sub.6 -alkyl alcohols. ##STR1##

Метод для производить alcoxylated смеси карбонила вообще формулы (I) (смесей ii1): R.sup.1.sub.a R.sup.2 C(OR.sup.3).sub.b при котором R.sup.1, R.sup.2 представляет водопод или C.sub.1 - C.sub.6 - алкил, R.sup.3 независимо намеревается C.sub.1 - C.sub.6 - алкил, а 0 или 1, б 2 или 3 with the proviso that сумма а и б 3, посредством анодной оксидации герминальных смесей dialcoxy вообще формулы (ii) (смесей II) при котором R.sup.4, R.sup.5, R.sup.6, R.sup.7 представляют водопод или C.sub.1 - C.sub.6 - алкил, R.sup.5, R.sup.6 представляет C.sub.1 - C.sub.6 - алкил или C.sub.1 - C.sub.6 - alcoxy, in the presence of C.sub.1 - C.sub.6 - алкиловый спирт (смеси III). Обычная смесь (смесь IV) использована как катодный деполяризатор целесообразный для электрохимической оксидации. Анодная оксидация и катодное уменьшение снесены вне в undivided клетку электролита in the presence of C.sub.1 - C.sub.6 - алкиловые спирты. ## ## STR1

 
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