Methods of forming metal alkoxides and methods of forming precursor
solutions of metal alkoxides suitable for the coating of glass in the
manufacture of electrochromic devices are disclosed. The method of forming
metal alkoxides involves dissolving the metal halide in an anhydrous
solvent and reacting it with an alcohol and (together with the addition of
the alcohol or subsequently) adding an epoxide, and then evaporating-off
the volatile components of the reaction product to leave a solid metal
alkoxide that is substantially free of halide. The alkoxide may then be
dissolved in a solvent including an alcohol (preferably ethanol)
containing a small proportion of water to produce a precursor solution
suitable for coating glass, the coating then being hydrolyzed to form a
sol-gel and then baked to remove volatile components and to yield a thin
layer of metal oxide.